Hydrogen embrittlement and stress corrosion cracking. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Hic testing apparatus is provided with specially made rack to keep the samples with minimum surface contact and all the specimens can be viewed during the test period easily. Part of the hydrogen produced by the cathodic corrosion reaction may permeate the steel by diffusion, and the balance is dissolved in the process electrolyte or released as. Hydrogen delayed cracking of highstrength weldable steels 7 these reactions take place in two steps. Hydrogen cracking its causes, costs and future occurrence. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Cracking is sometimes accompanied by surface blistering. Hydrogen induced cracking steel features, applications and. Hydrogen induced cracking of low strength steels in.
Hydrogen induced cracking test for naval steels american. Cathodic protection is one of the most effective methods of corrosion protection, however, it does not prevent the diffusion of hydrogen into the steel component. It primarily occurs in high strength low alloy steels. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Hydrogeninduced cracking an overview sciencedirect topics. Hydrogen induced cracking test instrument is supplied with standard size of 12l x 12w x 9h.
Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. When the crystal lattice is in contact or is saturated with atomic hydrogen, the mechanical. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Each form can build up enough pressure to produce internal cracks. The ductility loss brought about by hydrogen ingress is encountered even in unstressed bodies where such cracking is termed hydrogen induced cracking hic and is in phenomenological contrast to. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan.
Hydrogeninduced cracking results from atomic hydrogen being absorbed by solid metals. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. There is absence of direct experimental measurements supporting this mechanism. Hydrogen induced stress cracking hisc resistance and. Nace international has adopted the term hydrogeninduced cracking hic. Hydrogen blistering and hydrogen induced cracking hic. Hydrogen induced stress cracking hisc and dnvrpf112 article in measurement and control london institute of measurement and control 425. Hydrogen induced cracking hic assessment in a gas processing plant case study mohammed a abufour, mohammad. Modified 9cr1 mo steel, being air hardenable is highly susceptible to hydrogenassisted cracking hac.
The molecular form of hydrogen cannot diffuse and is stable. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Damage due to hydrogen embrittlement and stress corrosion. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Hydrogen atoms are very reactive and combine with almost all elements. The effect of hydrogen induced cracking on the integrity of.
The reason for this is the complexity of the damage mechanism which is dependent on the particular material and damaging medium. Hydrogen induced cracking is associated with absorption of hydrogen and a delayed time to failure incubation time during which hydrogen diffuses into regions of high triaxial stress. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h 2 s, corrosion reactions, cathodic protection, and operating in highpressure hydrogencontaining environments. This is hydrogen induced cracking by synergis education on vimeo, the home for high quality videos and the people who love them. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Hic test, hydrogen induced cracking test, step wise. The presence of hydrogen in the weld can cause significant quality and productivity issues, including stress in the microstructure of the base and weld metal that leads to hydrogeninduced cracking. Hydrogen induced cracking of low strength steels in geothermal fluids keith a. Proper cleaning of metal surface and preheating are the preventive steps to avoid alarming hydrogen induced cracking. Hydrogen induced cracking test tank test methods nace tm0284 astm g39 material of construction polypropylene, pvc, or glass capacities up to 55 liters cortest offers a variety of different hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on a metal sample in a hydrogen enriched. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Hydrogen induced crackinghydrogen induced cracking 2.
The occurrence of hydrogen embrittlement is a much researched phenomenon, known to cause mechanical property degradation and catastrophic failures. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Mechanism has been proposed by troiano and modified by oriani. Casing pipes used in sour service are prone to two forms of failure. Hydrogen induced cracking tests of high strength steels and. Weld metal hydrogen cracking in pipeline girth welds, proc. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. At intermediate stage adsorbed hydrogen atoms hads are present. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from. Hydrogenassisted cracking susceptibility of modified 9cr. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Corrosionpedia what is hydrogeninduced cracking hic. Specificationsgrades asmeastm saa 516 grades 606570.
Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen. The significance of these failures has led to research to define critical loading conditions for hisc, to allow confident design of components in future. Atomic hydrogen diffuses inside the metal and causes localized deformation, or even destroys the walls of the vessel. Hydrogen induced cracking hic or stepwise cracking swc is a specific kind of hydrogen provoked damage in carbon and low alloy steels operating in hydrogen sulphide containing environments, especially in steels used for pipelines and. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Hydrogen induced cracking and sulfide stress cracking evaluation of low alloy casing pipes. Hydrogen induced cracking hic in the oil and gas industry. Jun 05, 2017 hydrogen atoms are very reactive and combine with almost all elements. It was not until much later, however, that hic started to be investigated and gained recognition as a potential problem in pipelines as a result of pipeline failures. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. Hydrogen blistering has been recognized since the 1940s as a problem in vessel handling sour products. Josephicf the threshold pressures, p, of hydrogen and of deuterium gases necessary to cause crack propagation in aisi 4340 steel of 250 ksi yield strength have been determined as functions of planestrain stress intensity factor k. Defects hydrogen cracks in steels identification twi.
Susceptibility of indigenously developed modified 9cr1 mo steel plate and shielded metal arc welding. Hydrogen induced blistering when hydrogen is absorbed into metal and diffuses inward, it can precipitate as molecular hydrogen, at laminations, or inclusionmatrix interfaces. Induction heating is a good option for minimizing hydrogen. Hic test, hydrogen induced cracking test, step wise cracking. Susceptibility of indigenously developed modified 9cr1 mo steel plate. Detection of hydrogen induced cracks during inservice. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Material and metallurgical parameters were investigated.
In particular, the critical concentration for the onset of cracking at a given value of k fig. Mar 19, 20 modified 9cr1 mo steel, being air hardenable is highly susceptible to hydrogen assisted cracking hac. This form of cracking is especially detrimental and often observed in oil country tubular goods octg which are subjected to sour gas. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic. Hydrogen induced cracking hic on steel for corrosion. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may lose their mechanical properties. In this issue, the characteristic features and principal causes of hydrogen cracks are described. Hydrogen induced decohesion model dissolved hydrogen lattice hydrogen reduces the cohesive strength of the lattice, i. Naceastm g193 1 includes the following description of hydrogen blistering. The terms stepwise cracking, hydrogen pressure cracking, blister cracking o hydrogen induced stepwise cracking have been used in the past to describe cracking of this type, but are now considered obsolete. Equilibrium aspects of hydrogeninduced cracking of steels. Hydrogen cracking its causes, costs and future occurrence twi.
The results of the hydrogen induced cracking tests presented in this podcast can serve as a benchmark for the future development of high performance navy steels. Lichti, david m firth and annette d karstensen mpt solutions, po box 310, lower hutt, new zealand k. Hydrogen induced stress cracking hisc and dnvrpf112. The effect of hydrogen induced cracking on the integrity.
Hydrogeninduced stress corrosion cracking hiscc this type of damage is a transition form between the classical hydrogen embrittlement and stress corrosion cracking and applies in particular to hightensile steel in low aggressive water solutions, austentitic steel in diluted sulphuric acid, alloys in halogenide solutions and uranium alloys. Hydrogen induced cracking steel features, applications. Hydrogen induced cracking tests of high strength steels. The hydrogen induced cracking hic of asrolled steels has been investigated. Hydrogeninduced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering. The fact that the hydrogen induced cracking path in this steel is intergranular means that the calculated values of cc, and of fcif pertain to the boundaries between grains and between phases. Hydrogen gas introduced thinning thinning main crack main crack microcrack formed crack linkage. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. May 19, 2009 hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Refers to mechanical damage of metal caused by the presenceinteraction with hydrogen can be classified in to following types 1 hydrogen blistering 2 hydrogen embrittlement 3 hydrogen attack 4 decarburization hydrogen damage. Preheating and post heating are generally employed to avoid hac during fabrication. Hydrogen damage takes place at two temperature regions, elevated temperatures and temperatures at ambient.
Hydrogen induced cracking of subsea duplex stainless steel. Dec 01, 2000 although hydrogen induced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately. One key difference between hydrogen embrittlement and stress corrosion cracking, although very similar in many aspects, is their reaction to cathodic protection. Abstract as a first step, a literature survey was undertaken on hydrogen induced cracking hic phenomena. During welding, hydrogen is induced due to the moisture and organic compounds by the usage of cold cellulosic electrodes. Hydrogeninduced cracking is an important issue in the welding industry. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. For haz hydrogen cracking to occur, it is necessary for the hydrogen to migrate into the heat affected zone, which takes time. Hydrogen induced cracking hic from advanced ndt solutions. That means the hydroxyle ions decharge separately one by one. The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to.
As welding is carried out using matching consumables, the weld metal is also equally susceptible to hac. Hydrogen cracking may also be called cold cracking or delayed cracking. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. The hic may promote one mode of fracture in an alloy rather than another form normally observed in benign environments. Solute hydrogen atoms interact with an applied stress field zhydrogen induced local volume dilatation 2cm3mole in fe zhydrogen induced local elastic moduli changes measurements in nb solute hydrogen diffuses through normal interstitial lattice sites nils toward regions of lower chemical potential, i. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal. The ductility loss brought about by hydrogen ingress is encountered even in unstressed bodies where such cracking is termed hydrogen induced cracking hic and is in phenomenological contrast to catastrophic failures encountered by stressed bodies. Oct 07, 20 hydrogen induced cracking test for naval steels.
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